{"id":392,"date":"2019-03-14T02:25:34","date_gmt":"2019-03-14T02:25:34","guid":{"rendered":"http:\/\/www.sas.rochester.edu\/chm\/groups\/kennedy\/?page_id=392"},"modified":"2024-08-13T19:41:29","modified_gmt":"2024-08-13T19:41:29","slug":"publications","status":"publish","type":"page","link":"https:\/\/www.sas.rochester.edu\/chm\/groups\/kennedy\/publications\/","title":{"rendered":"Publications"},"content":{"rendered":"

\u2021<\/sup> Equal contributions. \u2020<\/sup> Undergraduate coauthor. * Corresponding Author<\/p>\n

Find Rose’s\u00a0ORCID<\/a>\u00a0(0000-0003-3681-819X),\u00a0Google Scholar<\/a>, and\u00a0My NCBI<\/a>\u00a0pages.<\/p>\n

23. Mechanistic insights on C(acyl)\u2212N functionalisation mediated by late transition metals<\/h6>\n

Pillai, V. G.; Malyk, K. R.; Kennedy, C. R.*\u00a0 Dalton Trans.<\/em> 2024<\/strong>, DOI: 10.1039\/d4dt01829j<\/a>.<\/p>\n

Invited submission to the New Talent: Americas Special Issue<\/em><\/p>\n

\"\"<\/p>\n

22. Deactivation Modes in Nickel-Mediated Suzuki\u2013Miyaura Cross-Coupling Reactions Using an NHC-Pyridonate Ligand<\/h6>\n

Kadam, A. A.;\u2021<\/sup> Afandiyeva, M.;\u2021<\/sup> Brennessel, W. W.; Kennedy, C. R.* Organometallics.<\/em> 2024<\/strong>, DOI: 10.1021\/acs.organomet.4c00235<\/a><\/p>\n

[original preprint] ChemRxiv. <\/em>2024<\/strong>, <\/em>DOI: 10.26434\/chemrxiv-2024-3xd1k<\/span><\/a><\/p>\n

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21. Secondary-Sphere Preorganization Enables Nickel-Catalyzed Nitrile Hydroboration<\/h6>\n

Afandiyeva, M.;\u2021<\/sup> Wu, X.;\u2021,\u2020<\/sup>\u00a0Brennessel, W. W.; Kadam, A. A.; Kennedy, C. R.* Chem. Commun.<\/em> 2023<\/strong>, 59<\/em>, 13450-13453. DOI: 10.1039\/D3CC04229D<\/a><\/p>\n

Invited submission to the 2023 Emerging Investigators Collection<\/em><\/p>\n

[original preprint] ChemRxiv.<\/em> 2023<\/strong>, DOI: 10.26434\/chemrxiv-2023-ks784<\/a><\/p>\n

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20. Insights into H+ <\/span>and e\u2013 <\/span>transfer by swapping Fe for Mn in a [NiFe] hydrogenase model.<\/h6>\n

Kadam, A. A.; Kennedy, C. R.* Chem. <\/em>2023<\/strong>, 9, 2370\u20132373. DOI: 10.1016\/j.chempr.2023.08.017<\/a> \u00a0(Invited Preview)<\/em><\/p>\n

19. Distinguishing Competing Mechanistic Manifolds for C(acyl)\u2013N Functionalization by a Ni\/N-Heterocyclic Carbene Catalyst System<\/h6>\n

Malyk, K. R.\u2021 <\/sup>; Pillai, V. G.\u2021 <\/sup>; Brennessel, W. W.; Leon Baxin, R.; Silk, E. S.\u2020<\/sup>; Nakamura, D. T.\u2020<\/sup>; Kennedy, C. R.*\u00a0 JACS Au.<\/em> 2023<\/strong>, 3, 2451\u20132457. DOI: 10.1021\/jacsau.3c00283 <\/a><\/p>\n

[original preprint]\u00a0 ChemRxiv.<\/em> 2023<\/strong>, DOI: 10.26434\/chemrxiv-2023-cb75z\u00a0<\/a><\/p>\n

\"\"<\/p>\n

18. Remixing the Secondary Coordination Sphere<\/h6>\n
Kadam, A. A.; Kennedy, C. R.*\u00a0 Trends Chem.<\/em> 2023<\/strong>, 5, 506\u2013508. DOI: 10.1080\/00958972.2022.211703 <\/a> (Invited Spotlight)<\/em><\/figure>\n
17. An Automated Variable Electric-Field DFT Application for Evaluation of Optimally Oriented Electric Fields on Chemical Reactivity<\/h6>\n
Hanaway, D. H.\u2020<\/sup>; Kennedy, C. R.* J. Org. Chem.<\/em> 2023<\/span><\/strong>, 88<\/em><\/span>, <\/span>106\u2013115<\/span>, DOI:\u00a010.1021\/acs.joc.2c01893<\/a><\/figure>\n
[original preprint] ChemRxiv.<\/em> 2022<\/strong>, DOI:\u00a010.26434\/chemrxiv-2022-4wr1m<\/a><\/p>\n
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16. Synthesis, Structure, and Hydroboration Reactivity of Anionic Nickel(0) Complexes Supported by Bidentate NHC-Pyridone Ligands<\/h6>\n

Afandiyeva, M.\u2021<\/sup>; Kadam, A. A.\u2021<\/sup>; Wu, X.\u2020,\u2021<\/sup>; Brennessel, W. W.; Kennedy, C. R.*\u00a0 Organometallics,<\/em>\u00a02022<\/strong>, 21<\/em>, 3014\u20133023. DOI: 10.1021\/acs.organomet.2c00439<\/a><\/p>\n

Selected as ACS Editors’ Choice<\/em><\/p>\n

[original preprint] ChemRxiv.<\/em> 2022<\/strong>, DOI: 10.26434\/chemrxiv-2022-gk2cs<\/a><\/p>\n

\"\"<\/p>\n

15. Synthesis and characterization of Ni(0) complexes supported by an unsymmetric C,N ligand<\/h6>\n
Craig, S. M.\u2020,\u2021<\/sup>; Malyk, K. R.\u2021<\/sup>; Silk, E. S.\u2020,\u2021<\/sup>; Nakamura, D. T. \u2020<\/sup>; Brennessel, W. W. ; Kennedy, C. R.*\u00a0 J.\u00a0Coord.\u00a0Chem.<\/em> 2022<\/strong>, 75<\/em>, 1841-1852. DOI: 10.1080\/00958972.2022.2117037<\/a><\/figure>\n
Invited contribution to Emerging Leaders Special Issue.<\/em>\"\"<\/p>\n

Mentored Publications<\/strong><\/h3>\n
14. Iron Catalyzed Synthesis and Chemical Recycling of Telechelic, 1,3-Enchained Oligocyclobutanes<\/h6>\n

Beromi, M. M.; Kennedy, C. R.<\/span> ; Younker, J. M.; Carpenter, A. E.; Mattler, S. J.; Throckmorton, J. A.; Chirik, P. J.*\u00a0 Nature Chem.<\/em>\u00a02021, <\/strong>13<\/em>, 156\u2013162.\u00a0DOI: 10.1038\/s41557-020-00614-w<\/a><\/p>\n

[Original Preprint] ChemRxiv<\/em>, 2020<\/strong>, 11994489.v1 . DOI: 10.26434\/chemrxiv.11994489.v1<\/a><\/p>\n

13. Iron-Catalyzed Vinylsilane Dimerization and Cross-Cycloadditions with 1,3-Dienes: Probing the Origins of Chemo- and Regioselectivity<\/h6>\n

Kennedy, C. R.<\/span>;\u2021 Joannou, M. V.;\u2021 Steves, J. E.; Hoyt, J. M.; Kovel, C. B.; Chirik, P. J.* ACS Catal.<\/i><\/span> 2021<\/span><\/strong>, 11<\/em><\/span>, 1368\u20131379. DOI: 10.1021\/acscatal.0c04608\u00a0<\/a><\/span><\/p>\n

12. Enantioselective Catalysis of an Anionic Oxy-Cope Rearrangement Enabled by Synergistic Ion Binding.<\/h6>\n

Kennedy, C. R.<\/span>; Choi, B. Y.\u00a7<\/sup>; Reeves, M.-G. R.\u00a7<\/sup>; Jacobsen, E. N.* Isr. J. Chem.<\/em>\u00a02020<\/strong>, 60<\/em>, 461\u2013474. DOI: 10.1002\/ijch.201900168<\/a><\/p>\n

Special issue dedicated to Profs. Stephen Buchwald and John Hartwig in celebration of their receipt of the 2019 Wolf Prize.<\/em><\/p>\n

11. Pyridine(diimine) Iron Diene Complexes Relevant to Catalytic [2+2]-Cycloaddition Reactions.<\/h6>\n

Kennedy, C. R.<\/span>; Zhong, H.; Joannou, M. V.; Chirik, P. J.* Adv. Synth. Catal.<\/em> 2019<\/strong>, 362<\/em>, 404\u2013416. DOI: 10.1002\/adsc.201901289<\/a><\/p>\n

Special issue in honor of Professor Eric Jacobsen’s 60th birthday.<\/em><\/p>\n

<\/div>\n
10. Cycloaddition of Isoprene for the Production of High-Performance Bio-Based Jet Fuel<\/h6>\n

Rosenkoetter, K.; Kennedy, C. R.<\/span>; Chirik, P. J.; Harvey, B. G.* [4+4]-Green Chem.<\/em> 2019<\/strong>, 21<\/em>, 5616\u20135623. DOI: 10.1039\/C9GC02404B<\/a><\/p>\n

9. Regio- and Diastereoselective Iron-Catalyzed [4+4]-Cycloaddition of 1,3-Dienes<\/h6>\n

Kennedy, C. R.<\/span>; Zhang, H.; Macaulay, R. L.; Chirik, P. J.*\u00a0 J. Am. Chem. Soc.<\/em> 2019<\/strong>, 141<\/em>, 8557\u20138573. DOI: 10.1021\/jacs.9b02443<\/a><\/p>\n

Highlighted as SYNFACT of the Month: <\/em>Knochel, P.; Balkenhohl, M.\u00a0Synfacts,<\/em> 2019<\/strong>,\u00a015, 0879.\u00a0DOI: 10.1055\/s-0039-1689843<\/p>\n

8. Selective [1,4]-Hydrovinylation of 1,3-Dienes with Unactivated Olefins Enabled by Iron Diimine Catalysts<\/h6>\n

Schmidt, V. A.;\u00a0Kennedy, C. R.<\/span>; Bezdek, M. J.; Chirik, P. J.* J. Am. Chem. Soc.\u00a0<\/em>2018<\/strong>,\u00a0140<\/em>, 3443\u20133453.\u00a0DOI:\u00a010.1021\/jacs.8b00245<\/a><\/p>\n

7. Chiral Thioureas Promote Enantioselective Pictet\u2013Spengler Cyclization by Stabilizing Every Intermediate and Transition State in the Carboxylic Acid-Catalyzed Reaction<\/h6>\n

Klausen, R. S.;Kennedy, C. R.<\/span>; Hyde, A. M.; Jacobsen, E. N.* J. Am. Chem. Soc.\u00a0<\/em>2017<\/strong>,\u00a0139<\/em>, 12299\u201312309.\u00a0DOI:\u00a010.1021\/jacs.7b06811<\/a><\/p>\n

6. Mechanism-Guided Development of a Highly Active Bis-thiourea Catalyst for Anion-Abstraction Catalysis<\/h6>\n

Kennedy, C. R.<\/span>\u2021<\/sup>; Lehnherr, D.\u2021<\/sup>; Rajapaksa, N. S.; Ford, D. D.; Park, Y.; Jacobsen, E. N.*\u00a0\u00a0J. Am. Chem. Soc.\u00a0<\/em>2016<\/strong>,\u00a0138<\/em>,\u00a013525\u201313528.\u00a0DOI:\u00a010.1021\/jacs.6b09205<\/a><\/p>\n

5. Synergistic Ion-Binding Catalysis Demonstrated via an Enantioselective, Catalytic [2,3]-Wittig Rearrangement<\/strong><\/h6>\n

Kennedy, C. R.<\/span>; Guidera, J. A.\u00a7<\/sup>; Jacobsen, E. N.* ACS Cent. Sci.<\/em>2016<\/strong>,\u00a02<\/em>,\u00a0416\u2013423.\u00a0DOI:\u00a010.1021\/acscentsci.6b00125<\/a><\/p>\n

<\/div>\n
4. Conformational Control of Chiral Amido-Thiourea Catalysts Enables Improved Activity and Enantioselectivity<\/h6>\n

Lehnherr, D.; Ford, D. D.; Bendelsmith, A. J.;\u00a0Kennedy, C. R.<\/span>; Jacobsen, E. N.*\u00a0 Org. Lett.<\/em>\u00a02016<\/strong>,\u00a018<\/em>, 3214\u20133217.\u00a0DOI:\u00a010.1021\/acs.orglett.6b01435<\/a><\/p>\n

3. Anion-Abstraction Catalysis: The Cooperative Mechanism of \u03b1-Chloroether Activation by Dual Hydrogen-Bond Donors<\/h6>\n

Ford, D. D.; Lehnherr, D.;\u00a0Kennedy, C. R.<\/span>; Jacobsen, E. N.* ACS Catal.\u00a0<\/em>2016<\/strong>,\u00a06<\/em>,\u00a04616\u20134620.\u00a0DOI:\u00a010.1021\/acscatal.6b01384<\/a><\/p>\n

2. On- and Off-Cycle Catalyst Cooperativity in Anion-Binding Catalysis<\/h6>\n

Ford, D. D.; Lehnherr, D.; Kennedy, C. R<\/span>.; Jacobsen, E. N.* J. Am. Chem. Soc.<\/em>\u00a02016<\/strong>,\u00a0138<\/em>,\u00a07860\u20137863.\u00a0DOI:10.1021\/jacs.6b04686<\/a><\/p>\n

1. The Cation-\u03c0 Interaction in Small-Molecule Catalysis.<\/h6>\n

Kennedy, C. R.<\/span>\u2021; Lin, S.\u2021; Jacobsen, E. N.* Angew. Chem. Int. Ed.\u00a0<\/em>2016<\/strong>,\u00a055<\/em>, 12596\u201312624. DOI:\u00a010.1002\/anie.201600547<\/a><\/p>\n

Patents<\/strong><\/h3>\n

4. Harvey, B. G.; Rosenkoetter, K. E.; Chirik, P. J.; Kennedy, C. R.<\/strong> Producing Cyclic Fuels from Conjugated Diene. Patent No. US10981846B1<\/a>, 2021. (Application No. US16\/542547)<\/p>\n

3. Carpenter, A. E.; Culcu, G.; Cai, I. C.; Lin, T.-P.; Chirik, P. J.; Kennedy, C. R.<\/strong>; Beromi, M. M. Improved Method to Produce Step Dienes. U.S. Provisional Application Filed: February 26, 2021.<\/p>\n

2. Chirik, P. J.; Kennedy, C. R.<\/strong>; Beromi, M. M. Depolymerization of Oligomers and Polymers Comprising Cyclobutane Units. U.S. Provisional Application No. 62\/966,863. Filed: January 28, 2020.<\/p>\n

1. Chirik, P. J.; Kennedy, C. R.<\/strong>; Russel, S. Oligomeric and Polymeric Species Comprising Cyclobutane Units. Patent No. US11001667B2<\/a>, 2019. (Application No. US16\/239938)<\/figure>\n<\/figure>\n","protected":false},"excerpt":{"rendered":"

\u2021 Equal contributions. \u2020 Undergraduate coauthor. * Corresponding Author Find Rose’s\u00a0ORCID\u00a0(0000-0003-3681-819X),\u00a0Google Scholar, and\u00a0My NCBI\u00a0pages. 23. Mechanistic insights on C(acyl)\u2212N functionalisation mediated by late transition metals Pillai, V. G.; Malyk, K. R.; Kennedy, C. R.*\u00a0 Dalton Trans. 2024, DOI: 10.1039\/d4dt01829j. Invited submission to the New Talent: Americas Special Issue 22. Deactivation Modes in Nickel-Mediated Suzuki\u2013Miyaura Cross-Coupling … <\/p>\n

Continue reading “Publications”<\/span><\/a><\/p>\n","protected":false},"author":12,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"footnotes":""},"class_list":["post-392","page","type-page","status-publish","hentry"],"_links":{"self":[{"href":"https:\/\/www.sas.rochester.edu\/chm\/groups\/kennedy\/wp-json\/wp\/v2\/pages\/392","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.sas.rochester.edu\/chm\/groups\/kennedy\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/www.sas.rochester.edu\/chm\/groups\/kennedy\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/www.sas.rochester.edu\/chm\/groups\/kennedy\/wp-json\/wp\/v2\/users\/12"}],"replies":[{"embeddable":true,"href":"https:\/\/www.sas.rochester.edu\/chm\/groups\/kennedy\/wp-json\/wp\/v2\/comments?post=392"}],"version-history":[{"count":68,"href":"https:\/\/www.sas.rochester.edu\/chm\/groups\/kennedy\/wp-json\/wp\/v2\/pages\/392\/revisions"}],"predecessor-version":[{"id":9312,"href":"https:\/\/www.sas.rochester.edu\/chm\/groups\/kennedy\/wp-json\/wp\/v2\/pages\/392\/revisions\/9312"}],"wp:attachment":[{"href":"https:\/\/www.sas.rochester.edu\/chm\/groups\/kennedy\/wp-json\/wp\/v2\/media?parent=392"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}